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Equipment & Technology Guide

Reduction and Precipitation of Chromium from Electroplating Wastewater

Two-Stage Waste Treatment for Hexavalent Chromium

Waste treatment of hexavalent chromium is a two-stage process. [S1] The hexavalent chromium is first reduced to the trivalent chromium ion; then it can be precipitated as chromium hydroxide. [S1]

Alternative Removal Approaches Reported in the Literature

Ion-exchange elimination of hexavalent chromium [Cr (VI)] from electroplated industrial wastewater has been investigated as a treatment option. [S2]

Uptake of hexavalent chromium in electroplating wastewater by hydrothermally treated and functionalized sand has been studied, and its sustainable reutilization for glass production has been considered. [S3]

Batch adsorption using two different nano-adsorbents—purified carbon nanotubes (P-CNTs) and polyhydroxylbutyrate functionalized carbon nanotubes (PHB-CNTs), both produced through catalytic chemical vapour deposition (CCVD) method—has been investigated for the removal of heavy metals, including As, Pb, Cr, Cd, Ni, Cu, Fe, and Zn, from industrial electroplating wastewater. [S4]

Pre-Treatment by Precipitation and Flocculation

Electroplating wastewater containing Cr (VI), Cu 2+ and Ni 2+ is a mixture from electroplating production lines in the electroplating park. [S5] The wastewater was pretreated by precipitation and flocculation before utilizing them in present experiments. [S5]

Summary of the Reduction–Precipitation Sequence

The reduction step converts hexavalent chromium to the trivalent chromium ion, which is then precipitated as chromium hydroxide. [S1] Other reported handling options for hexavalent chromium in electroplating wastewater include ion-exchange elimination [S2], adsorption onto hydrothermally treated and functionalized sand with potential reuse in glass production [S3], and batch adsorption using P-CNTs and PHB-CNTs produced by the CCVD method for mixed heavy-metal removal [S4]. Mixed electroplating wastewater containing Cr (VI), Cu 2+ and Ni 2+ has been subjected to precipitation and flocculation as a pre-treatment step. [S5]

Related equipment and engineering reading

References

  1. AP-42, Volume I, Section 12.20: Electroplating
  2. Removal of hexavalent chromium from electroplating wastewater ...
  3. Uptake of Hexavalent Chromium in Electroplating Wastewater by Hydrothermally Treated and Functionalized Sand and Its Sustainable Reutilization for Glass Production
  4. Selected Heavy Metals Removal From Electroplating Wastewater by Purified and Polyhydroxylbutyrate Functionalized Carbon Nanotubes Adsorbents
  5. Effective removal of chromium, copper, and nickel heavy metal ...
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